A dictionary of chemical solubilities : inorganic / by Arthur Messinger Comey.

  • Comey Arthur Messinger, 1861-
Date:
1896
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Licence: Public Domain Mark

Credit: A dictionary of chemical solubilities : inorganic / by Arthur Messinger Comey. Source: Wellcome Collection.

Provider: This material has been provided by the Royal College of Physicians of Edinburgh. The original may be consulted at the Royal College of Physicians of Edinburgh.

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    Anhydrous salt is sol. in 2784 pts. HaO at 5^ in lo,901 pts. NH^OII + Afi (1 :3) (0-96 p. gr.); in 1386 pts. NH^Cl + Aq (1 : 70) ; in ;S67 pts. NH^Cl + Aq (1:7); in 3014 pts. s'H^Cl (1 pt.) + NH^OH(0-9() sp.gr.) (10 pts.) + (60 pts.); in 32,827 pts. magnesia mixture. Fresenius, Z. anal. 3. 206.) Anhydrous salt is sol. in 4389 pts. NHjNOj t-Aq (1 : 50); in 2561-5 pts. KCl + Aq (1 :165); 11 1422 pts. ammoniacal solution of 3'5 g. tar- aric acid in 250 ccm. H.^O ; in 933 5 pts. niiuoniacal solution of 2*5 g. citric acid in 250 cm. H.,0. (ruUer, Z. anal. 10. 62.) I +iH:,0. Soi. in 2656 pts. HjO at 15°; in 15,038 pts. ^H40H +Aq (1 : 3) (0-96 sp. gi-.) ; in 844 pts. JH^Ol + Aq (1:7); in 1315 pts. NH^Cl + Aq i : 70); in 2871 pts. NH4CI (1 pt.) + NH40H D-96 sp. gr.) (10 pts.) + Aq (60 pts.). (Fre- cnius.) I 1000 pts. pure HoO dissolve 0*14 pt. salt; lOOO pts. NHjCl + Aq (containing 100 pts. *'H/:i) dissolve 0-95 pt. salt; 900 pts. H„0 f-100 pts. NH4OH (sp. gi\ 0-880) dissolve 0-07 it, salt. (Field, Cheni, Soc. 11. 6.) I +6H„0. SI. efflorescent. SI. sol. in H2O. ♦ery si.' sol. in NHjOH + Aq. .mmonium manganous arsenate, NH4MnAs04 + 6H2O. Nearly insol. in cold HjO ; easily sol. in dil. jids ; insol. in alcohol. mmonivun sodium arsenate, NH4NaHAsO. + 4H2O. Sol. in HjO. (Uelsmann, Zeit. f. ges. Nat. e. 347.) mmonivun sodiiun hydrogen arsenate, 1 f g(NH4)3Na3( As04)4 + 6H2O. :. in HoO. (Filhol and Senderens, C. R. I -19.) mmonium strontium arsenate, NH .SrAsO^ + t. mmonium uranyl arsenate, NH4(U02)ASO4 + ' lIoO. ' >\. in HjO, HC2H3O2, and saline solutions i I4CI +Aq ; sol. in mineral acids, (Puller, il. 10. 72.) mmonium vanadium arsenate, XH4(V02)2As04, and (NH4)2HAs04 + ^'V02)2H2AS04. Arseniovanadate, ammonium, aony arsenate { !). il. in H2O ; insol. in acids after ignition, lien fresh is sol. in cone, boiling HC1 + r ind si. sol. in HNO:, + Aq. (Dumas.) irium arsenate, Ha;j(As04)2. 1000 pts. jiurc H2O di8.solve 0-55 pt. 4(As04)2; 1000 pts. NH4C1 + Aq (containing * pts. NH4CI) dissolve 1-95 pts. Ba3(A.s04)2; 0 pts. H.p + lOO i)ts. NHjOH + Aq (si), gr. 0-88) dissolve 0-03 pt. Ba3(As04)2. (Field, lem. Soc. 11. 6.) I. in cold HNO3, and HCl + Aq (Herzolius) ; I f4O,;, and HC2H3O2 -t- A(j. (Autlion.) Solubility in HjO is not increased by presence of NH4, Na, or K salts. (Laugier.) Notpptd. in jiresence of Na citrate. (Spillcr.) + UH.,0. (vSalkowsky, J. pr. 104. 129.) Barium hydrogen arsenate, BaHAs04 +1 JHgO. Very si. sol. in H.fi, but deconi]). thereby into Ba3(As04)2 and BaH4(As04)2. (Berzelius.) SI. sol. in cold acids. + n.fi. SI. sol. in either BaCl2 + Aq or Na.,HAs04 + Aq. (Maiunene, J. B. 1864. 237.) Barium <c<mhydrogen arsenate, BaH4(As04)2. Easily sol. in H„0. (Setterberg, Bcrz. J, B. 26, 206.) Barium arsenate, acid, BaO, 2As20j + 4H2O. Very si, sol. in HoO. (Mitscherlich.) Barium pyroaxBen&te, Ba2As207, Insol. in HoO, but decomp. thereby into BaHAs04 + H26. (Lefevre, C. R. 108. 1058.) Barium potassium arsenate, BaKAsOj. SI. decomp. by cold HjO ; rapidly sol. in dil, acids, (Lefevre, A, oh, (6) 27. 1,) Barium arsenate chloride, 3Ba3(As04)2, BaCl2. Insol. in H2O; sol. in dil. HNOg + Aq. (Lechartier, C. R. 65. 172.) Bismuth arsenate, basic, BiAs04, SBigOs. Insol. in HoO. Sol. in mineral acids. (Cavazzi, Gazz. ch. it. 14. 289.) 5Bio03, 2AS2O6 + 8H2O. Min. Rhacjite. Easily sol, in HCl + Aq; si, sol, in HNO3 + Aq. Bismuth arsenate, BiAs04 + ^HgO. Insol, in HgO. Insol. in HNO3 + Aq in presence of H3ASO4, or alkali arsenates + Aq ; sol. in HCl + Aq. (Salkowsky, J. pr. 104, 129.) Not wholly insol. in HNO.j +Aq. (Schneider, J. pr. (2) 20. 418.) Very sol. in H3ASO4 + Aq. (Dumas,) Insol. in Bi(N03)., +Aq. (Dumas.) Sol. in Bi(N03)3 + Aq. (Salkowsky.) Insol, in cone. Bi(N03)3 + Aq containing a small quantity of HNO3. (Schneider.) Bismuth copper arsenate, Bi2Cu2oAsioH4407o= Bi203, 20CuO, 5AS2O5 + 22H2O. Min. Mixite. Decomp. by dil. HNOs + Aq into insol. BiAs04, and C)u3(As04)2, which goes into solution. (Dana.) Bismuth uranyl arsenate, Bi2(As04)2, SBiOgHa, (U02)3(AS04)2. Min. JValpurgite, Cadmium arsenate, Cd3(As04)2. Pjit. (Salkowsky, J. pr. 104. 129.) 2CdO, AsgOfi. (Lefevre, C. R. 110. 405.) 5CdO, 2As,p5 + 5H,,0. Ppt. (Salkowsky.) Cadmium jf^z/yoarsenate, CdaAsjO-. (de Schulten.) Cadmium hydrogen arsenate, CdHAs04 + HoO. Dceoiim. l)y HoO. (Duuiel, B. 12. 1279.) CdIl4(As04)o + 2HoO. Decomp. by excess of H2O. (de Schulten, Bull. Soc. (3) 1. 473.)