A dictionary of chemical solubilities : inorganic / by Arthur Messinger Comey.

  • Comey Arthur Messinger, 1861-
Date:
1896
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Licence: Public Domain Mark

Credit: A dictionary of chemical solubilities : inorganic / by Arthur Messinger Comey. Source: Wellcome Collection.

Provider: This material has been provided by the Royal College of Physicians of Edinburgh. The original may be consulted at the Royal College of Physicians of Edinburgh.

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    slowly converted into an allotropic modifica- tion (?). Partially decomp. by cone. HNO3. Slowly but wholly dissolved by hot cone. HNO3. SI. sol. in cone. KOH + Aq. (Arppe.) Sol. in about 100 pts. boiling KOH + Aq, so cone, that it solidifies on removing the lamp. (Muir, Chem. Soc. 51. 77.) Bi,Pr„ 2H.,0. (Bodeker, A. 123. 61.) Does not exist. (Hoffmann and Geuther.) Bismuth iodide, Bilg. Not attacked by cold HoO, but by boiling, BiOI is formed. 100 pts. absolute alcohol dissolve 3^- pts. salt at 20°. (Gott and Muir, Oheiii Soc. 67. 138.) Sol. in HNO3, and HI + Aq, from which it is repptd. by HgO or alcohol. Sol. in KI + Aq or KOH 4- Aq. (Rammelsberg.) 100 pts. methylene iodide dissolve 015 pt. Bilg at 12°, and very little more at higher temperatures. (Retgers, Z. anorg. 3. 343.) Bismuth hydrogen iodide, Bilg, HI + 4H2O. (Arppe, Pogg. 44. 248.) Bismuth calcium iodide, 2BiI.j, Calo + lSHjO. Deli(iuescent; decomp. by HoO. (Linau, Pogg. 111. 240.) Bismuth magnesium iodide, 2Bil3, MgIo + 12H2O. Deliquescent; decomp. by HjO. (Linau, Pogg. 111. 240.) Bismuth potassium iodide, Bil^, 4KI. P])t. (Arppe, Pogg. 44. 237.) BiL„ 3KI. (Astre, C. R. 110. 1137.) Bil;„ 2KI. Sol. in acetic ether. (Astre.) +-4H20- Sol. in small amt. HgO without pptn., but decomp. by much H2O. Bil.„ 2KI, HI. (Arppo.) 2Bi'l3, 3KI + 2H2O. (Astre.) Bil.„ Kl + H.p. Decomp. by HoO. (Nickles, C. R.'si. 1097.) 2Bil3, KI. Sol. in acetic ether. (Astre.) Bismuth sodium iodide, Bilj, Nal + HjO. Deliquescent; decomp. by HgO. (Nickles, C. R. 51. 1097.) 2BiI.„ 3NaI + 12H20. As above. (Linau, Pogg. ill. 240.) Bismuth zinc iodide, 2Bil3, Znl2 + 12H20. Very deliquescent. (Linau, Pogg. 111. 240.) Bismuth iodide ammonia, BiL„ 3NH3. Doooiu]). by HoO. (Rammelsberg.) Bismuth iodide zinc bromide. Sol. in H.,0. (Linau, Pogg. 111. 240.) Bismuth rft'oxide, BigOa. Sol. in cone. HNOg + Aq. Decomp. by strong acids, and boiling KOH + Aq. Bismuth </ ioxide, BiaOa. Insol. in H2O. Sol. in cone, acids. Min. Bismilc. Easily sol. in HNOg + Aq. See also Bismuthous hydroxide. Bismuth ^f^roxide, Bi204. S<il. in cone. HCl + Aq, witli evolution of CI ; in oxygen acids with evolution of 0. Less easily sol. in cone. HoSO. than in HNO^, or HCl + Aq. Bismuth oxide, Bi40fl (?). (Hollniaun and Geuther.) Bismuth ^w/i<oxide, Bi205. Sol. in dil. acids. Combines with H2O to form bismuthic hydroxide, wliieh see. (Haso- broek, B. 20. 213.) Bismuth oxybromide, etc. Sec Bismuthyl bromide, etc. Bismuth phosphide, BiP. (Cavazzi.) Bismuth ^riselenide, BioSeg. Insol. in H2O, alkalies, or alkali sulphides + Aq ; si. attacked by HCl + Aq ; oxidised by HNOg + Aq. (Schneider, Pogg. 94. 628.) Min. Frenzelilc. Bismuth selenochloride, BiSeCl. Not attacked by H2O ; very si. sol. in HC1 + Aq ; easily and completely sol. with decomp. in HNOg + Aq. (Schneider.) Bismuth (Z/sulphide, 61282+2H2O (?). Insol. in HoO. Decomp. by HGl + Aq. Bismuth i/ isulphide, 61083. Insol. in H.,0. Easily sol. in moderately dil. HNOg + Aq, and cone. HCl + Aq, with sejiiua- tion of S. Insol. in alkalies, alkali sulplndes, Na^SaOs, or KCN + Aq ; insol. in NH4CI, 01 NH4N63 + Aq (Brett). Insol. in potassium thioearbonate +Aq. (Rosenbladt, Z. anal. 26. 15.) Min. Bismuthinile. Easily sol. in HNO.| + Aq. Bismuth cuprous sulphide, 61283, CujS. Insol. in HoO. Sol. with decomp. in HNO ; t Aq. (Schneider, J. pr. (2) 40. 564.) Min. Emplcctonite. Bismuth potassium sulphide, BioSj, KjS. (Schneider, Pogg. 136. 460.) Bismuth sodium sulphide, BioSg, NaoS. (Scliueider.) Bismuth sulphide telluride, BioSg, 2Wh^e^. j Min. Tctradymile. Sol. in HNO3 witli sepax4 ation of S. BioSo, 2BioTe. Min. Joseitc. As above. Bismuth sulphochloride, BiSCl. Insol. in ILO or dil. HCl + Aq. Sol. in cone. HCl, or HNO3 +Aq. Decomp. byalknli. s + Aq. (Schneider, Pogg. 93. 464.) Bismuth sulphoiodide, BiSI. Not attacked by boiling HoO, and dil. acids. Decomp. by hot cone. HCl + Aq, and HNO.,+ Aq. KOH + Aq dissolves out I2. (Schm i l i Pogg. 110. 114.) Bismuth telluride, BioTe3. Min. Tetradi;IIIifc. Sol. in Hj^0.j +A.|. See aho Bismuth sulphide telluride.