A dictionary of chemical solubilities : inorganic / by Arthur Messinger Comey.

  • Comey Arthur Messinger, 1861-
Date:
1896
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Licence: Public Domain Mark

Credit: A dictionary of chemical solubilities : inorganic / by Arthur Messinger Comey. Source: Wellcome Collection.

Provider: This material has been provided by the Royal College of Physicians of Edinburgh. The original may be consulted at the Royal College of Physicians of Edinburgh.

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    BORATE, LEAD 58 hot solutions of aiuniouium salts, ospycia ly Moniuni iiitrato, in CaCla + Aq, and also ,V sol. in dilutii mineral acids at 50 . (Ditto, C. K. 80. 190, f)61.) + 7H.jO. Sol. in HaO without dccomi).; 1 1. solution contjiins 2 g. salt. (Ditte, C. R. 96. 1603.) ^ CaH407. Decomp. by H2O. (Blouut, C. JN. B4. -208.) + 3H..0. (Ditte, C. R. 96. 1663.) + 41L0. Min. Ikchilitc. + 611,0. 'i,Vn\. Boracalcile. Sol. in acids. Ca..H/Oii. (Ditto, C. R. 77. 785.) + 3H.,0. Min. randcrmitc, Priccile. + 6H.';0. CaB86,3 + r2H20. (Ditte, C. R. 96. 1663.) CajBu.Oig. Precipitate. Calcium ferrous borate silicate, CaaFeBjSijOio. .Min. IlomilUc. Easily sol. in HCl + Aq. Calcium magnesium borate, CaO, MgO, 3BoO;) + 6H,0. Min. Hydrohoracitc. Somewhat sol. in H2O. Biisily sol. in warm HCl + Aq or HNO^ + Aq. 3CaO, 3MgO, iB^Og. (Ditte, C. R. 77. 894.) Calcium sodium borate,Ca3BioOi8,Na.jB509 +15, or 21H.,0. Min. Natrohoromleitc, Ulexite. Decomp. by toiling with HjO. Sol. in acids. CaoNa4B,2022+15H20. Min. Franklanditc. 511. sol. in HoO ; easily sol. in HCl, and HNO3 + Aq. 3alcium borate chloride, Ca^BaOfi, CaCl2. Decomp. quickly by moist air or HoO, slowly jy absolute alcohol. (Chatelier, C. R. 99. 276.) 3alcium borate silicate, 2CaO, B2O3, 2Si02 + H2O. Min. Datolitc. Sol. in HCl + Aq with separ- ition of gelatinous silica. + 2H0O. Min. BotmjoUte. CaO, B2O3, SiOa- Min. Danburite. Very si. ittackod by HCl + Aq before ignition. iJbromous borate. Precipitate. Sol. in free acids; insol. in 3orax + Aq. (Moberg.) Jhromic borate, 7Cro03, 4B2O3. Insol. in H^O ; sol. in excess of borax+ Aq. Hebberling, C. C. 1870. 122.) Jhromic magnesium borate, 3Cr203, 6Mg0, 2B,P3. Not attacked by acids. (Ebelmen, A. eh. 3) 33. r,2.) 2Cr203, 9MgO, 3B2O3. (Mallard, C. R. 105. 260.) JobaltouB borate, 3CoO, 2B2O3 + 4H2O. SI. sol. in HjO. (Rose, Pogg. 88. 299.) 3CoO, B,,03. (Mallard, C. R. 106. 1260.) iSnpric borate, basic. Composition depends on temperature and !oncentration of solutions. Boiling H2O dis- lolves out all the boric acid. Sol. in acids ; ilowly sol. in hot cone. NH4CI +Aq. Cupric borate ammonia, CUB4O7, 4NH3 + Eflloro.scent. Can be recrystallised from a little NH.,OH + Aq. (Pasternack, A. IBl, 227.) Didymium borate, DiB03. Insol. in II.,0 acidulated with HCl + Aq. (Cleve, Bull. Soc. (2) 43. 363.) Di2(B407).,. Insol. in H.p; sol. in acids. (Frorichs and Smith, A. 191. 355.) Glucinum borate, basic, 5010, B2O3. Insol. in ll.p ; sol. in acids. (Kruss and Moraht, B. 23, 735.) Ferrous borate. Ppt. HoO dissolves out all the boric acid. (Tiinnerman.) Ferric borate, Fe.,(B02)8 + 3H20. I'pt. Insol. in H2O. Min. Lagonitc. Sol. in acids. 2FaP3, 3B2O3. (Mallard, C. R. 106, 1260.) 6Fe20.„ B2O3 + 6H2O. Ppt. (Rose, Pogg. 89. 473.) 9Fe203, B2O3 + 9H2O. Ppt. (Rose.) Ferric magnesium borate, 3Fe203,6MgO, 2B2O3. Insol. in H2O. Sol. in cone. HCl + Aq. (Ebelmen, A. ch. (3) 33. 53.) 2Fe203, 9MgO, 3B0O3. (Mallard, C. R. 105. 1260.) Ferroferric magnesium borate, 3MgO, FeO, Fe203, B2O3. Min. Ludivigile. Slowly sol. in HCl + Aq, when finely powdered. Ferrous borate bromide, 6FeO, 8B2O3, FeBi-g. Slowly sol. in hot HN03 + Aq. (Rousseau and Allaire, C. R. 116. 1445.) Ferrous borate chloride, 6FeO, 8B2O3, FeCl2. Slowly sol. in hot HNOy + Aq. (Rousseau and Allaire, C. R. 116. 1195.) Lanthanum borate, 2La203, B2O3. (Nordeuskjbld, Pogg. 114. 618.) La2(B407)3. Ppt. (Smith.) Formula is LajBgOjs + a;H20. (Cleve, B. 11. 910.) Lead borate, basic, 2PbO, B20., + 2H20. Ppt. 4PbO, '6li.Jj., + m.fi. Ppt. + 5H2O. Ppt. 6PbO, 5BoO., + 6H20. Ppt. 8PbO, 3B2O3 + 8H2O. Ppt. 9PbO, 5B2O3 + 9H2O. P))t. (Rose, Pogg. 87. 470.) Lead borate, Pb(B02)2 +H2O. Insol. in HjO. Easily sol. in dil. HNO3, or boiling HC2H.,02 + Aq. Decomp. by H,2S04, HCl, akso by boiling KOH, or NaOH+Aq. Insol. in alcohol. (Herapath, Phil. Mag. (3) 34. 375.) Sol. in NH4CI + Aq ; sol. in sat. NaCl + Aq. 2l'])0, 3B.p., + 4ll20. (Heraj)ath.) PbB407 + 4li.p. Slightly sol. in pure H..0, but insol. in solutions of Na salts as Na2B407 + A(|. (Soulieiran.)