A dictionary of chemical solubilities : inorganic / by Arthur Messinger Comey.

  • Comey Arthur Messinger, 1861-
Date:
1896
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Licence: Public Domain Mark

Credit: A dictionary of chemical solubilities : inorganic / by Arthur Messinger Comey. Source: Wellcome Collection.

Provider: This material has been provided by the Royal College of Physicians of Edinburgh. The original may be consulted at the Royal College of Physicians of Edinburgh.

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    Caesium lead i!^ /!7 «chloride. Sec Chloroplumbate, csesium. Csesiuni magnesium chloride, CsCl, MgCl2+ 6H2O. Sol. iu H2O. (Wells and Campboll, Z. anorg. 5. 275.) Caesium manganous chloride, CsCl, MnCl2+ 2H2O. Not deliquescent; sol. in H2O. (Saunders, Am. Ch. J. 14. 143.) 2CsCl, MnClj. (Godeffroy.) + 2iH20. (Godeffroy.) + 3H2O. Sol. in H2O. Cone. HCl + Aq precipitates anhydrous salt from aqueous solu- tion. (Godeflroy, B. 8. 9.) The only salt which exists contains 2H2O. (Saunders, Am. Ch. J. 14. 143.) Csesium mercuric chloride, CsCl, HgClz- 100 pts. solution sat. at 17° contain 1*406 pts. CsHgClg. Not decomp. by HjO. Insol. in absolute alcohol, but sol. on diluting with I vol. H,0. (Wells, Sill. Am. J. 144. 221.) 2CsCl,HgCl2. Easily sol. in H2O and dil. HCl + Aq; insol. in cone. HCl + Aq. (Godef- froy.) 3CsCl, HgCl2. Decomp. by H2O ; on re- crystallising from HgO, CsCl,HgCl2 is finally formed. (Wells, Sill. Am. J. 144. 221.) CsCl, 5HgCl2. Decomp. by H2O. (Wells.) Csesium nickel chloride, 2CsCl, NiCl2. As the corresponding Cu salt. Csesium silver chloride, 2CsCl, AgCl. Easily decomp. by HoO. (Wells and Wheeler, Sill. Am. J. 144. 155.) Csesium tellurium chloride. Sec Chlorotellurate, csesium. Cffisium thalUc chloride, 3CsCl, TlCl3-f2H20. Sol. in 36-4 pts. HjO at 1^° and 3 pts. at 100°. (Godeflroy, Zeitsch. d. allgem. osterr. Apothekcrv. 1880. No. 9.) Csesium stannic chloride. Sec Chlorostannate, csesium. Csesium zinc chloride, 3CsCl, ZnCl2. Sol. in HgO. (Wells and Campbell, Z. anorg. 5. 275.) 2CsCl, ZnCl2. Easily sol. in HgO and dil. HCl-f-Aq. Insol. in cone. HCl-hAq. (Godef- froy.) Csesium chloroiodide, CsCLjL Properties as CsBrClI. (Wells.) CSCI4I. SI. sol. in H2O, from which it can be recrystallised without decomp. (Wells and Wheeler.) Csesium mercuric chloroiodide, Cs2HgCl2l2- Decomp. instantly by H2O to Hgl2. (Wells.) Csesium hydroxide, CsOH. Very deliquescent, and sol. in HjO. Sol. iu alcohol. Csesium iodide, CsL Sol. in n„0. Csesium iriiodide, Cslg. 1 ccm. sat. Csl + Aq dissolves 0-0097 g. Cslj, and sp. gr. of solution is 1'154. Only si. decomp. l)y solution in H2O. Much more sol. in alcohol than in HjO. Not immediately decomp. by ether. (Wells, Sill. Am. J. 143. 17.) Csesium ^>c?i<«iodide, Cslg. Csesium lead iodide, CsPblj. SI. sol. in hot Csl + Aq. (Wheeler, Sill. Am. J. 145.129.) Csesium mercuric iodide, Csl, 2Hgl2. Deeomp. by HjO finally into HgL. (Wells,, Sill. Am. J. 144. 221.) 2CsI, 3Hgl2. Decomp. by HgO finally into Hgl2. Csl, Hglg. As above. 2CsI, Hgl2. Decomp. by H2O; insol. inu| alcohol. 3CsI, Hgl2. As above. Csesium silver iodide, Csl, Agl. (Penfield, Z. anorg. 1. 100.) Csesi\un tellurium iodide. Sec lodotellurate, csesium. Csesium zinc iodide, 3CsI, Znl2. 1 Sol. in HjO. (Wells and Campbell, Z. anorg. ' 5. 275.) 2CsI, Znlg. As above. Calcium, Ca. Decomp. H2O violently. Slowly attacked.i| by cold H2SO4. Dil. H2S04 + Aq or HClH-Ar] attack violently and dissolve. Dil. HNOj + A ] o.xidises, but fuming HNO3 scarcely attacks-, even on boiling. (Bunsen and Matthiessen.) i Not attacked by anhydrous alcohol. (Lies-.>j Bodart and Jobin, A. ch. (3) 54. 364.) I Calcium bromide, CaBr2. Very deliquescent. 100 pts. H2O dissolve— at 0° 20° 40° 60° 105° 125 143 213 278 312pts.CaBr2., (Kremers, Pogg. 103. 65.) Sp. gr. of CaBrg-l-Aq. at 19-5° containing: 5 10 15 20 25 % CaBra, 1-044 1-089 1-139 1-194 1-252 30 35 40 45 50 % CaBr2. 1-315 1-385 1-461 1-549 1-641 (lii-emers, Pogg. 99. 444, calculated by Gerlach 1 Z. anal. 8. 285.) Very sol. in alcohol. (Henry.) + 6H2O. Calcium mercuric bromide. Decomp. by HgO. (v. Bonsdorfl.) Calcium bromide ammonia, CaBrg, 6NH3. Sol. in H2O. (Rammelsberg, Pogg. 65. 239.' Calcium stannic bromide. Sec Bromostaimate, calcium. Calcium chloride, CaCL. Very deliquescent. Very sol. in HjO witi evolution of heat.