First outlines of a dictionary of solubilities of chemical substances / by Frank H. Storer.

  • Francis Humphreys Storer
Date:
1864
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Licence: Public Domain Mark

Credit: First outlines of a dictionary of solubilities of chemical substances / by Frank H. Storer. Source: Wellcome Collection.

Provider: This material has been provided by the National Library of Medicine (U.S.), through the Medical Heritage Library. The original may be consulted at the National Library of Medicine (U.S.)

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    d^zcidL ACETATES. Acetate of Jervin. Soluble in water. Acetate of Lanthanum. Easily soluble in water. (Mosander.) Acetate of Lead. I.) normal, or mono. Soluble in water. Spar- ta anurous, ingly soluble in hot absolute al- & = C4H3Pb04 + 3Aq Slightly efflorescent in dry ^EXj Salt air-. soluble * °-5 p1- of boiling water. (Wenzel.) Soluble in 1 pt. of water at 38°. (Wenzel in his Verwandtschuft, p. 308 [T.].) Thompson (in his St/stem, 2. 641) affirms that this statement of Wenzel is a mistake. Soluble in 1.63 pts. of cold water; the saturated solution containing 37 % of it; still more readily soluble in hot water. (M. R. & P.) Soluble in 1.714 pts. of water at 18.75°. (Abl, from Oesterr. Zeitschrijl, fir Pharm., 8. 201, in Canstatt's Jahresbericht,fiir 1854, p. 76.) 100 pts. of boiling water dissolve about 29 pts. of it. cold water retains in solution about 27 pts. of it. (Bostock, Nicholson's Journ., 11. 79, [T.]) The aqueous solution saturated at 10° contains 11.4% of it. (Eller.) r 7.7% (Mussembrock.) 12.5° 24.4% (Hassenfratz, Ann. de Chim., 28. 291.) The aqueous solution saturated at 15° is of 1.236673 sp. gr., and contains dissolved in every 100 pts. of water at least 45.653 pts. of the salt. (Michel & Krafft, Ann. Ch. et Phys, (3.) 41. pp. 478, 482.) The aqueous solution saturated at its boiling-point (101.70°) contains 41.5% of the dry salt; or 100 pts. of water at 101.7° dissolve 70.94 pts. of it; or 1 pt. of the dry salt is soluble in 1.41 pts. of water at 101.7°. (T. Griffith's, Quar. J. Sci., 1825, 18. 90.) Melts in its water of crystallization at about 57°. An aqueous Contains per solution of cent of the sp. gr salt, (at 12.5°) 1.0070 .... 1 1.0140 2 1.0211 3 1.0283 4 1.0366 5 1.0430 6 1.0505 7 1.0580 8 1.0655 .... 9 (Hassenfratz. Ann. de Chim., 28. 302.) Tolerably soluble in spirit, less so in absolute alco- hol. Soluble in 8 pts. of alcohol. (M. R. & P.) Soluble in 1 pt. of strong alcohol at 68°. (Cited in Thompson's System of Chem., 2. 285.) 100 pts. of alcohol, of 0.835 sp. gr., dissolve 7.85 pts. of it at 15.5°. (Ibid., p. 641.) Ether precipitates it from its alcoholic solution. Very readily solu- ble in boiling creosote, the solution becoming solid on cooling. (Reiehenbach.) When one equivalent of 04 Hspb °»in aqueous so- lution, is mixed with a solution of an equivalent of nitrate of potash (K0,N05) 0.09 of it are decom- posed to nitrate of lead, which maybe precipitated by adding alcohol, while 0.91 of it remain un- changed ; when mixed with a solution of an equiv- alent of nitrate of baryta (Ba 0,N05), 0.22 of it are decomposed as before, while 0.78 of it remain un- changed ; when mixed with a solution of an equiv- alent of nitrate of strontia (Sr0,N05), 0.33 of it are decomposed while 0.67 of it remain unchanged. An aqueous Contains per solution of cent of the sp. gr. salt. (at 12.5°) 1.0731 ... 10 1.0891 12 1.1055 14 1.1221 16 1.1330 18 1.1560 20 1.1740 22 1.1928 ... 24 II.) sesqiribasic. The crystals dissolve in 0.9 3Pb0,2C4H303&-t-Aq pts. of water at 12.75°; there- fore more abundantly than the normal salt. The saturated aqueous solution can still dissolve both monobasic and terbasic ace- tate of lead. Less soluble in alcohol than in wa- ter, but more soluble in alcohol than the normal acetate. The anhydrous salt dissolves in strong alcohol; on adding water to this solution trisacetate of lead is precipitated, while the normal salt remains in solution. (Payen, in Berzelius's Lehrb.) III.) din. Soluble in less than 1.5 pts. of 2PbO,C4H303&+Aq,&2Aq water. Tolerably sol- uble in weak spirit. Soluble in about 30 pts. of alcohol of 90%. In- soluble in absolute alcohol. (Schindler.) IV.) tris. Very soluble in water, though less 3 Pb 0, C4 H3 03 + Aq so than the normal salt. Sol- uble in 5.56 pts. of boiling wa- ter. Soluble in 18 pts. of cold water. Insoluble in strong alcohol. (Berzelius, Lehrb.) Soluble in spirit and in dilute wood-spirit, though less so than in water. Slightly soluble also in wood- spirit of 97%, but not in alcohol of 97%. (Payen.) Soluble in a saturated aqueous solution of the ses- quibasic salt. V.) hexa. Sparingly soluble in boiling wa- 6Pb 0, C4 H3 03 + 3HO ter, from which it crystallizes on cooling. Acetate of peroxide of Lead. Pb 02, 3 C4 H3 ti3 Acetate of Lead & of Potash. Tolerably 3 Pb 0,2 KO, 3 C4 H3 03 soluble in hot water. (Tad- dci.) Acetate of Lead & of Soda. 2 C4 H3 Pb 04 ; C4 H3 Na 04 + 3 Aq Acetate of Lead & of Uranium. Read- C4 H3 Pb 04; Ur2 03, C4 H3 03 + 6 Aq ily soluble in wa- ter. (Wertheim, loc. cit.) Acetate of Lead with Anacardate of C4H3Pb04; CMH31Pb07 Lead. Insoluble in water. Insoluble in cold alcohol, but is partially decomposed by long-continued washing therewith, or immediately by boiling al- cohol. Decomposed by ether. Acetate of Lead with Chloride of Lead. 5 C4 H3 Pb04; Pb CI +15 Aq Efflorescent. Easily sol- uble in water. Decom- posed by alcohol. (Poggiale.) Acetate of Lead with HtdroKinone. Dif- 2C4H3Pb04;C12H604 + 3Aq ficultly soluble in cold, easily soluble in boiling water. Almost insoluble in cold alco- hol ; decomposed by boiling alcohol, and ether. (Kolbe's Lehrb., 1. 467.) Acetate of Lead, with Picrate of Lead. I.) C4H3PbN04; C12H2Pb(N04)302 + 4Aq Readily soluble in water. The solution is decomposed by evapo- ration. II.) C4 H3 Pb 04; 2 C12 H2 Pb (N 04)3 02, Pb 0 + 8 Aq De- com- posed by long-continued boiling with water. Acetate of Lead with ThioNaphtamate C4H3Pb04; CjoHgPbNSjOg of Lead. Sparingly soluble in cold, more readily soluble in hot water. (Piria, Ann. Ch. et