First outlines of a dictionary of solubilities of chemical substances / by Frank H. Storer.

  • Francis Humphreys Storer
Date:
1864
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Licence: Public Domain Mark

Credit: First outlines of a dictionary of solubilities of chemical substances / by Frank H. Storer. Source: Wellcome Collection.

Provider: This material has been provided by the National Library of Medicine (U.S.), through the Medical Heritage Library. The original may be consulted at the National Library of Medicine (U.S.)

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    Vot Sd^-cl (Destouches.) Soluble in alcohol of 60%. (Tromms- dorff.) Ether precipitates it from the alcoholic so- lution. Readily soluble in boiling, less so in cold creosote. (Reichenbach.) Soluble in both anhy- drous and hydrated acetic acid. Soluble in warm, less soluble in cold hydrate of anisyl. When one equivalent of C4H3k()4, in aqueous solution, is mixed with a solution of an equivalent of nitrate of lead (PbO,NO5),0.92 of it are decomposed to nitrate of potash, which may be precipitated by adding alcohol, while 0.08 of it remain unchanged; when mixed with a solution of an equivalent of nitrate of strontia (SrO, N05) 0.67 of it are decom- posed as before, while 0.33 of it remain unchanged ; when mixed with a solution of an equivalent of nitrate of baryta (BaO, N06), 0.27 of it are decom- posed, while 0.73 of it remain unchanged ; when mixed with a solution of an equivalent of sulphate of soda (NaO, S03), 0.62 of it are decomposed, while 0.38 of it remain unchanged. (Malaguti, Ann. Ch. et Phys., 1853, (3.) 37. 203.) II.) ■ Anhydrous bin Acetxte of Potash. Less 2C4H3K04, C8Ha06 deliquescent than the normal salt. Exceedingly soluble in water. (Gerhardt, Ann. Ch. et Phys., (3.) 37. 317.) III.) Bin Acetate of Potash. Deliquescent. (Ordinary.) though less so than the C4H3K04,C4H404& + 6Aq normal salt. Easily sol- uble in water, and alcohol. More soluble in hot than in cold absolute alcohol. Acetate of Potash & of Thoria. Soluble in water. Acetate of Potash & of Uranium. Easily 2C4H3(Ur203)03; C4HsK04 + 2Aq soluble in cold water; partially decomposed by boiling water. (Wertheim, Ann. CLetPhys., (3.) 11. 62.) Acetate of Propyl. (Acetate of Trityl. Propyl Acetic Ether.) C10H10O4 = C4H3(C6H,)O4 ZtoiAcETATE of Proptlene. Insoluble in a (BinAcetate of Tritylene (of Gerhardt). small quan- Propyl Glycol diAcetique.) jjj_ DUj. ,jjg_ C14 Hu 08 = C8 H6 (C6 H6») 08 gojv'es m abmU 10 times its volume of water. Soluble in all pro- portions in alcohol, and ether. (A. Wurtz.) Acetate of Propylenyl. Vid. Acetate of Allyl. Acetate of Quinidin. Readily soluble in water ; more soluble than the acetate of quinine. Acetate of Quinink. Sparingly soluble in cold, readily soluble in boiling water. Soluble in alcohol. Acetate of sesquioxide of Rhodium. Soluble In boiling water. (Berzelius, Lehrb.) Acetate of sesquioxide of Rhodium & of Soda. Very readily soluble in water. Insoluble in alcohol. (Berzelius.) Acetate of Salicylous Acid. Vid. AcetoSalicyl. Acetate of Silver. Difficultly soluble in C4H3Ag04 water; being one of the least soluble of the metallic acetates. (Otto-Graham.) Soluble in 100 pts. of cold water. (Cliencvix.) Readily soluble in cyanide of potassium. Acetate of Silver & of Uranium. Easily 2 C4 H3 (Ura 03) 08 ; C4 H3 Ag 04 + 2 Aq soluble with- out decom- position in cold, but is decomposed by boiling wa- ter. (Wertheim, Ann. Ch. et Phys., (3.) 11. 61.) Acetate of Silver with Propionate of C4H3Ag04; C6H5Ag04 Silver. Difficultly soluble in water. Acetate of Soda. I.) normal. Slowly efflorescent. Soluble in 2.86 a = C4 H3 Na04 -f6Aq pts. of cold water, the sat- (Ordinary Commercial.) uratc{J solution containing 25.91% of it. (Bergman, 5. 78, [T.].) Soluble in 3.9 pts. of water at 6°. 2.4 37°. « 1.7 48°. (Osann.) Soluble in 3 pts. of water at 18.75°. (Abl, from Oesterr. Zeitschrift fur Pharm., 8. 201, in CamtatCs Jahresbericht,fur 1854, p. 76.) The aqueous solution saturated at 12.5° contains 51.7% of it. (Hassen- fratz, Ann. de Chim., 28. 291.) 100 pts. of water at 15.5° dissolve 35 pts. of it. (Ure's Diet.) The aqueous solution saturated at its boiling-point (124.4°) contains 60% of the dry salt; or, 100 pts. of water at 124.4° dissolve 150 pts. of it; or 1 pt. of the dry salt is soluble in 0.66 pt. of water at 124.4°. (T. Griffiths, Quar. J. Sci., 1825,18. 90.) When heated, it melts in its water of crystalli- zation, and if the fluid is covered with a layer of oil it will not solidify as it becomes cold, unless it be agitated as by adding a crystal of the salt. (Berzelius, Lehrb.) An aqueous Contains An aqueous Contains solution of per cent solution of per cent sp. gr. of the salt. sp. gr. of the salt, at 12.5^ at 12 5= 1.0028 ... 1 1.0685 ... 22 1.0058 2 1.0751 24 1.0087 3 1.0817 26 1.0117 4 1.0883 28 1.0146 5 1.0955 30 1.0176 6 1.1018 32 1.0206 7 1.1090 34 1.0237 8 1.1165 36 1.0267 9 1.1242 38 1.0299 10 1.1320 40 1.0361 12 1.1399 42 1.0424 14 1.1482 44 1.0488 16 1.1567 46 1.0553 18 1.1656 48 1.0619 ... 20 1.1755 ... 50 (Hassenfratz, Ann. de Chim., 28. 303.) An aqueous Contains 1 pt. of solution of crystallized Ace- sp. gr. tate of Soda in at 12.5° pts. of water. 1.008 50 ... . 1.010 40 1.014 30 1.017 20 1.030 10 1.060 5 Boils at °C. 100.18° 100.2° 100.3° 100.4° 100.8° 101.7° l-,0° 2 103.6° (R. Brandes, Brandes's Archiv., 1827, 22. 147.) In a solution con- _, taining for 100 pts. Ihe temperature of water, pts. of dry of ebullition Difference. Acetate of Soda. ls elevated. 0.0 0° . . . 9.9 l 99 17.6 2 77 24.1 3 6!s 30.5 4 6.4 36.7 5 6.2 42.9 6 6.2 49.3 7 6.4 55.8 8 6.5 64.2 9 6.6 69.2 10 6.8 76.2 11 7.0